I haven't practiced enough to give you much advice about technique, but I will tell you if you want to arc weld aluminum, you will need a TIG machine capable of doing AC. HF start will make for less tungsten contamination.
DC electrode negative creates more heat in the work piece, but electrode positive breaks up the surface oxides. So in aluminum welding we have to break up the oxides with electrode positive, however that will melt the tungsten, thus why we use AC, to get the best of both worlds.
Also, you will need a stainless steel wire brush that has not been contaminated by use on any other metal.
Oh, also aluminum has great heat conductivity and thus acts like a heat sink, which is why you need more amps vs welding steel of the same size.
Edit... I should add that the do make electrodes for doing stick welding using electrode positive DC. They work, but are not popular, and are better suited for large work pieces.
Edit 2... Just realized you are probably talking about casting and not welding... LOL.